Changes

2-acetyl pyrroline (abbreviated: APY, ACPY, or AP) is a more volatile but more potent form of THP. It has a significantly stronger odor and lower odor threshold in wine than ATHP. It can also be found in damp pearl millet, toasted bread, taco shells, tortilla chips, boiled potatoes, cooked sweet corn products, roasted sesame seeds, pan-fired green teas, cured tobacco leaves, peanut and pumpkin seed oils, honey, several soy-based products, and more aromatic rice such as Indian Basmati, as well as many other foods. APY has also been detected in a pale lager beer from Bavaria <ref>[https://link.springer.com/article/10.1007/BF01190873 Primary odorants of pale lager beer. Peter Schieberle. 1991.]</ref>. APY from microbial metabolism is primarily produced by heterofermentative LAB (see [[Tetrahydropyridine#Lactic_Acid_Bacteria|below]]). In food, APY formation is due to cooking and thought to be associated with Maillard reactions, and its presence ages out quickly in food. For example, Schieberle (1989) showed that heating up yeast and sucrose produced APY, simulating how APY could be produced during baking bread <ref><[https://pubs.acs.org/doi/10.1021/bk-1989-0409.ch025 Formation of 2-Acetyl-l-pyrroline and Other Important Flavor Compounds in Wheat Bread Crust. Peter Schieberle. 1989. DOI: 10.1021/bk-1989-0409.ch025.]</ref>. It is extremely volatile; so much so that the food industry has created powdered forms of APY to increase the flavor stability of some foods associated with it. Some plants such as rice crops, Pandan leaves (''Pandanus amaryllifolius''), "bread flowers" (''Vallaris glabra''), Myabi muskmelon fruit, chempedak fruit and jackfruit contain varying levels of APY naturally <ref name="Snowdon"></ref><ref name="Grbin_1996" /><ref name="Adams_2005">[http://pubs.acs.org/doi/abs/10.1021/cr040097y Chemistry of 2-Acetyl-1-pyrroline, 6-Acetyl-1,2,3,4-tetrahydropyridine, 2-Acetyl-2-thiazoline, and 5-Acetyl-2,3-dihydro-4H-thiazine:  Extraordinary Maillard Flavor Compounds. An Adams and Norbert De Kimpe. 2005.]</ref><ref>[https://www.sciencedirect.com/science/article/pii/S1672630823001105 Abiotic and Biotic Factors Controlling Grain Aroma along the Value Chain of Fragrant Rice: A Review. Ayut Kongpun, Tonapha Pusadee, Pennapa Jaksomsak, Kawiporn chinachanta, Patcharin Tuiwong, Phukjira Chan-In, Sawika Konsaeng, Wasu Pathom-Aree, Suchila Utasee, Benjamapohn Wangkaew, Chanakan Prom-U-Thai. Rice Science. 2023. https://doi.org/10.1016/j.rsci.2023.11.004.]</ref>.