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Dimethyl Sulfide

No change in size, 15:27, 12 July 2018
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In summary, the new model predicts that the 15 minute pasteurization rest produces the least amount of DMS (~5 µg/L), while the 15 minute boil produces the most DMS (~35 µg/L). Note that 35 µg/L of DMS is still below the recommended 100 µg/L of DMS that should be allowed to go into the fermenter <ref name="Scheuren2016mbaa"></ref>.
===Kettle Souring and Effects Impacts of pH===
The normal procedure for [[Wort_Souring|kettle souring]] techniques is to boil the wort a second time after the pH has been lowered in order to kill the ''Lactobacillus'' souring culture. The lactic acid fermentation by the ''Lactobacillus'' generally results in a wort pH of around 3.0 - 3.6, at which time the wort is boiled to kill the ''Lactobacillus''. In this case, yet another consideration is the effect impact of low pH on the decomposition of SMM into DMS. The [[Dimethyl_Sulfide#Mashing_and_Boiling|half-life table above]] demonstrates that a decrease of -0.3 pH increases the half-life by 5.5 minutes at 100°C. Unfortunately, we do not have data to show how the much lower pH values that are achieved after souring wort will affect the half-life of SMM <ref name="Scheuren2014"></ref>, but assuming the effect impact is linear then the conversion of SMM into DMS during the second boil would be greatly reduced. Assuming the effect of pH on SMM half-life is linear, and that every -0.3 pH increases the half-life by 5.5 minutes at 100°C, the half-life table could hypothetically be updated to include data that looks something like what we present in the first column below. This indicates that wort boiled after souring probably does not create significant amounts of DMS from SMM.
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