Changes

! Ester !! Precursors !! Flavor/Odor Threshold !! Molecular Formula !! Notes

| [[Ethyl acetate]] (fruity, solventy) || [[Acetic Acid]] || 33ppm (odor), 100ppm (flavor) || || High flavor threshold; pear-like in low amounts and nail polish in high amounts. Increases production with higher temperatures and oxygen

| Ethyl lactate butyrate (fruitypineapple, creamymango, rum tropical fruit <ref>[http://www.aroma-chemicalflavoractiv.com/products/ethyl-lactatebutyrate-beer-flavour-standards/ Best Aroma websiteEthyl Butyrate Beer Flavour Standard. Ethyl LactateFlavorActIV. Retrieved 086/1520/2015.]</ref><ref>[https://books.google.com/books?id=avYMy82EBuAC&pg=PA384&lpg=PA384&dq=ethyl+lactate+flavor&source=bl&ots=AZufxA6Htu&sig=rTbNo4rOSBY_6kuhGDtW_JqQ5oA&hl=en&sa=X&sqi=2&ved=0CD0Q6AEwBWoVChMI35jXjuirxwIVyKOICh0klgDF#v=onepage&q=ethyl%20lactate%20flavor&f=false Dictionary of Flavors. Dolf De Rovira. John Wiley & Sons, Feb 28, 2008. Pg 384.]</ref>) || [[Lactic Butyric Acid]] || 0.2 ppm-1.66 ppm 4ppm (odorflavor) <ref>[http://hazmapwww.nlmflavoractiv.nih.govcom/products/categoryethyl-details?id=1179&table=copytblagents Hazbutyrate-beer-flavour-Map, standards/ Flavoractiv. Ethyl Lactate odor thresholdbutyrate. Retrieved 1/18/2015.]</ref> || Increases || Low levels of production by some species of Brettanomyces; production decreases with higher amounts of Lactic Acid acidity <refname="yakobson1">[http://www.brettanomycesproject.com/dissertation/pure-culture-fermentation/impactpure-ofculture-initial-concentration-of-lacticfermentation-aciddiscussion/ Yakobson, Chad. The Brettanomyces Project]. Impact Pure Culture Fermentation Characteristics of Brettanomyces Yeast Species and Their Use in the Initial Concentration of Lactic Acid on Brewing Industry. Pure Culture FermentationDiscussion. Retrieved 6/16/20152011.]</ref>

| Phenethyl acetate Ethyl caproate (sweet, honeyfruity, pineapple, banana, rose flower likeapple or aniseed) || Acetyl-CoA, 2-phenylethanol || 3-5ppm (odor), 5-10ppm (flavor) Caproic acid <ref>[https://books.google.com/books?id=A8OyTzGGJhYC1b1CAgAAQBAJ&pg=PA1521RA2-PA320&lpg=PA1521RA2-PA320&dq=PhenethylEthyl+acetate+flavorcaproate+thresholdprecursors&source=bl&ots=Ygvq_JFvhQmyHXfoVz9f&sig=06Lj57fWYemcXizkEHnYzwfOXX8fHGkce4UmeJVC4M3Kk4TXUCO-Nc&hl=en&sa=X&ei=Zzip68VOqjFY-nVOPCKI61oQSFwIGABQtyASpmoHoCA&ved=0CEAQ6AEwBA0CEQQ6AEwBA#v=onepage&q=PhenethylEthyl%20acetate20caproate%20flavor%20threshold20precursors&f=false Encyclopedia of Food Microbiology. BurdockBatt, George Carl A]. Fenaroli's Handbook of Flavor Ingredients, Fifth Edition. CRC Academic Press. 2005Sep 28, 1999. pg 1521Pg 320. ]</ref> || 0.2ppm (flavor) <ref>[http://www.ymdbaroxa.cacom/compoundsbeer/YMDB00574 YMDBbeer-flavour-standard/ethyl-hexanoate/ Aroxa. ethyl hexanoate. Retrieved 1/18/2015.]</ref> || || Also known as Ethyl hexanoate, Ethyl butyl acetate, and butylacetate <ref>[http://www.chemspider.com/Chemical-Structure.29005.html Chemspider. Ethylhexanoat. Phenethyl acetateRetrieved 1/18/2015.]</ref>

| Ethyl butyrate caprylate (Sweet, waxy, fruity and pineapplewith creamy, mangofatty, tropical fruit mushroom and cognac notes <ref>[http://www.flavoractivthegoodscentscompany.com/products/ethyl-butyrate-beer-flavour-standardsdata/ rw1056351.html Ethyl Butyrate Beer Flavour StandardOctanoate. FlavorActIVThe Good Scents Company. Retrieved 65/2028/2015.]</ref>) || [[Butyric Acid]] || 0.4ppm Caprylic acid (flavorcontained in buckwheat; produced by yeast autolysis) and ethanol <ref>[httphttps://www.flavoractivyoutube.com/products/ethylwatch?v=2QgXptgw1ys Chop & Brew -butyrate-beer-flavour-standards/ FlavoractivEpisode 37: Influence of Mashing on Sour Beer Production by Michael Tonsmeire. NHC 2014 Presentation. Ethyl butyrateAt 26 minutes. Retrieved 15/1828/2015.]</ref> || Low levels of production by some species of Brettanomyces; production decreases with higher acidity 15ppb (flavor) <ref name="yakobson1">[http://www.brettanomycesprojectleffingwell.com/dissertation/pure-culture-fermentation/pure-culture-fermentation-discussion/ Yakobson, Chad]esters.htm Esters Detection Tresholds & Molecular Structures. Pure Culture Fermentation Characteristics of Brettanomyces Yeast Species and Their Use in the Brewing IndustryLeffingwell & Associates. Pure Culture Fermentation Discussion. 2011 Retrieved 5/28/2015.] </ref>|| || Also known as ethyl octanoate

| Ethyl Decanoate (brandy, fruity, oily, grape) || Capric Acid (Decanoic acid) and ethanol <ref>[http://en.wikipedia.org/wiki/Ethyl_decanoate Wikipedia. Ethyl Decanoate. Retrieved 1/18/2015.]</ref> || || || Also known as Ethyl caprate, Ethyl caprinate, and Capric acid ethyl ester <ref>[http://www.michiganbrewersguild.org/docs/Gary-Spedding_off-flavor-notes_2014WC.pdf Spedding, Gary. Flavor notes for Michigan Craft Guild Conference. 2014.]</ref>

| Ethyl caproate lactate (sweet, fruity, pineapplecreamy, banana, apple or aniseed) || Caproic acid rum <ref>[http://www.aroma-chemical.com/ethyl-lactate/ Best Aroma website. Ethyl Lactate. Retrieved 08/15/2015.]</ref><ref>[https://books.google.com/books?id=1b1CAgAAQBAJavYMy82EBuAC&pg=RA2-PA320PA384&lpg=RA2-PA320PA384&dq=Ethylethyl+caproatelactate+precursorsflavor&source=bl&ots=myHXfoVz9fAZufxA6Htu&sig=fHGkce4UmeJVC4M3Kk4TXUCO-NcrTbNo4rOSBY_6kuhGDtW_JqQ5oA&hl=en&sa=X&eisqi=ip68VOqjFY-tyASpmoHoCA2&ved=0CEQQ6AEwBA0CD0Q6AEwBWoVChMI35jXjuirxwIVyKOICh0klgDF#v=onepage&q=Ethylethyl%20caproate20lactate%20precursors20flavor&f=false Encyclopedia Dictionary of Food MicrobiologyFlavors. Batt, Carl ADolf De Rovira. Academic Press. Sep John Wiley & Sons, Feb 28, 19992008. Pg 320384.]</ref> ) || [[Lactic Acid]] || 0.2ppm 2 ppm-1.66 ppm (flavorodor) <ref>[http://wwwhazmap.nlm.aroxanih.com/beergov/beercategory-flavourdetails?id=1179&table=copytblagents Haz-standard/ethyl-hexanoate/ Aroxa. ethyl hexanoate. Retrieved 1/18/2015Map, Ethyl Lactate odor threshold.]</ref> || Also known as Ethyl hexanoate, Ethyl butyl acetate, and butylacetate || Increases production with higher amounts of Lactic Acid <ref>[http://www.chemspiderbrettanomycesproject.com/Chemicaldissertation/pure-culture-fermentation/impact-of-initial-concentration-Structureof-lactic-acid/ Yakobson, Chad.29005.html ChemspiderThe Brettanomyces Project. EthylhexanoatImpact of the Initial Concentration of Lactic Acid on Pure Culture Fermentation. Retrieved 16/1816/2015.]</ref>

| Ethyl caprylate valerate (Sweet, waxyfruity, acidic, fruity and pineapple with creamy, fattyapple, mushroom green, berry and cognac notes tropical <refname="goodscents_ethylvalerate">[http://www.thegoodscentscompany.com/data/rw1056351rw1000701.html Ethyl Octanoate. The Good Scents Company. Ethyl Valerate article. Retrieved 508/15/2015.]</ref>) <ref name="Joseph">[http://www.ajevonline.org/content/suppl/2015/07/28/66.3.379.DC1/Supplemental_Data.pdf Supplemental Data for:Joseph, C.M.L., E.A. Albino, S.E. Ebeler, and L.F. Bisson. Brettanomyces bruxellensis aroma-active compounds determined by SPME GC-MS olfactory analysis. 2015.]</ref>) || Caprylic Valeric Acid (pentanoic acid (contained in buckwheat; produced by yeast autolysis) and , ethanol || 1500-5000 ppm <refname="Fenaroli_ethylvalerate">[https://wwwbooks.youtubegoogle.com/watchbooks?id=15HMBQAAQBAJ&pg=PA638&lpg=PA638&dq=ethyl+valerate+threshold&source=bl&ots=avVr8PQQ_p&sig=zm81_lhLU86VJ4jBNnm4I9nnxDw&hl=en&sa=X&ved=0CDIQ6AEwBGoVChMImYrEl6usxwIVAjmICh1HGwEs#v=2QgXptgw1ys Chop onepage& Brew - Episode 37: Influence q=ethyl%20valerate%20threshold&f=false Fenaroli's Handbook of Mashing on Sour Beer Production by Michael TonsmeireFlavor Ingredients, Fifth Edition. George A. NHC 2014 PresentationBurdock. At 26 minutes CRC Press, Dec 3, 2004. Retrieved 5Pg 638.]</ref> || C₇H<sub>14</28sub>O<sub>2</2015.]sub> <ref name="goodscents_ethylvalerate"> </ref> || 15ppb Valeric acid quantities found in beer are minimal (flavor0-1 ppm) and below odor threshold <ref>[http://wwwonlinelibrary.leffingwellwiley.com/estersdoi/10.htm Esters Detection Tresholds & Molecular Structures1002/j.2050-0416.1974.tb03598.x/pdf Organoleptic Threshold Values of Some Organic Acids in Beer. Leffingwell & AssociatesSigmund Engan. Retrieved 51973.]</ref><ref>[https://28books.google.com/2015books?id=allg4XxlOM4C&pg=PA91&lpg=PA91&dq=valeric+acid+beer&source=bl&ots=Pfb6EL9ufV&sig=sTb3gjpv7dlQNBOmGBPuDXJegLs&hl=en&sa=X&ved=0CB4Q6AEwAGoVChMIx9Kstp6sxwIVzCqICh2r7wc3#v=onepage&q=valeric%20acid%20beer&f=false Aroma of Beer, Wine and Distilled Alcoholic Beverages. L. Nykänen, H. Suomalainen. Springer Science & Business Media, May 31, 1983.] </ref> || Also . Ethyl valerate is also known as ethyl octanoatepentanoate <ref name="goodscents_ethylvalerate"></ref>. Also found in apples, bananas, guava, stawberry, cheeses, rum, whiskey, cider, sherry, grape wines, cocoa, coffee, honey, and passion fruit <ref name="Fenaroli_ethylvalerate"></ref>.

| Isoamyl Acetate acetate (banana) || [[Acetic Acid]], Isoamyl alcohol || 1.1ppm (flavor) <ref>[http://www.aroxa.com/beer/beer-flavour-standard/isoamyl-acetate/ Aroxa. Isaoamyl acetate. Retrieved 1/18/2015.]</ref> || || Produced by certain ''Saccharomyces'' strains but concentrations are generally reduced by ''Brettanomyces''. <ref>[http://onlinelibrary.wiley.com/doi/10.1002/j.2050-0416.1982.tb04061.x/abstract Spaepen and Verachtert, 1982. Esterase Activity in the Genus ''Brettanomyces'']</ref>